Regardless of what happened to her husbands, that's a lot of grief and suffering. Death, abandonment, infidelity (hers or theirs) all take their toll upon a soul. I expect it is reasonable to say that this woman had experienced more than her fair share of sorrow.
I expect that she had her moments, face down on the ground, weeping and crying out to God her "why me's" and her "how long's". Since she didn't even bother with the formality of a marriage ceremony with the man she was currently with, I expect she had perhaps given up on things ever changing. Perhaps she thought that she was beyond the hope of her prayers being heard and answered.
I doubt she had very many friends, if any. She went to the well in the heat of the day, the other women of the village would have already come and gone in the early hours, when it was cooler. She probably avoided them. I can certainly relate to the desire to avoid others due to fear of judgment or rejection.
So the woman goes to the well, in the heat of the day to draw water, and low and behold the Messiah, the King of Kings and Lord of Lords meets her there. What an amazing experience for her, a life changing experience, an answer to all the prayers, a source of hope that overcomes all the hardships and sorrows, a friend above any earthly friend.....she, the lowly woman with five husbands and at least one lover, the woman who must go to the well in the heat of the day to avoid the other women, comes face to face with Jesus.
The experience was life changing, for she who came to the well in the heat of the day, now goes out to tell others, Come and see a man who told me everything I ever did. Do you think he might be the Christ?”
Orthodox Church history tells us that the Samaritan woman whom Christ met at the well in the heat of the day, was later baptized by the apostles and took the name of Photini which means “the enlightened one". It is said that she traveled to Rome, preaching the gospel and that she was martyred for her faith in the year of our Lord 66.
You can read more of the Orthodox church history on Photini here:
In my devotional reading this morning I read about the Samaritan woman at the well and how God is not deaf to our groaning prayers. He will come, He will answer, He will do so in His time, and in just the right manner. If the wait seems long, take heart and do not cease to pray, to not give up, press onwards, for Jesus will come. "So keep praying and cultivate patient, long-suffering faith. There will be a day when you will find Him unexpectedly at the well of your deepest thirst."
Quote is from the book Things Not Seen by Jon Bloom